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## GUJARAT TECHNOLOGICAL UNIVERSITY

## Program Name: Diploma in Engineering

## Level: Diploma

## Branch: Chemical Engineering

Course / Subject Code : DI02000031

Course / Subject Name  : Industrial Chemistry

w. e. f. Academic Year:

2024-25

Semester:

2

Category of the Course:

Basic Science Courses (BSC)

| Prerequisite:   | Fundamental  calculations.                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                           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                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            | of                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  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                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                             | basic                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                       | Arithmetic                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  | for                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                               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| Rationale:      | Industrial Chemistry deals with the transformation of raw materials into required  products  that  are  beneficial  to  humanity  using  physical  and  chemical  processes  and fundamental principles of chemistry.   In chemical industries, during processes various organic compounds are used. The  knowledge  of  physical  and  chemical  properties  of  these  compounds  helps  the  diploma engineers how to use and control processes effectively. Therefore, for a  diploma  engineer,  the  skills  and  fundamental  information  related  to  industrial  chemistry are essential for understanding the parameters which control chemical  processes such as  Halogenation, Oxidation,  Isomerisation,   Nitration,  Pyrolysis,  Hydrogenation,    Hydrohalogenation,  Ozonolysis,  Polymerization,  Sulphonation,  Alkylation, Acetylation, Esterification, Dehydration, Phase rule, Adsorption, etc.  Production of synthetic materials like fertilizers, pesticides, dyes, drugs, plastics,  cosmetics,  etc.  used  by  human  beings  is  harmful  to  living  beings  and  pollutes  environment.  For  this,  presently,  scientists  are  trying  to  develop  methods  to  produce environmentally favourable chemical synthesis by Green Chemistry and  judicious use of them. India is a rising player in the global semiconductor industry  and  will  explore  to  grow  semiconductor  ecosystem.  There  will  be  a  futuristic  development of a sustainable semiconductor in industries. | Industrial Chemistry deals with the transformation of raw materials into required  products  that  are  beneficial  to  humanity  using  physical  and  chemical  processes  and fundamental principles of chemistry.   In chemical industries, during processes various organic compounds are used. The  knowledge  of  physical  and  chemical  properties  of  these  compounds  helps  the  diploma engineers how to use and control processes effectively. Therefore, for a  diploma  engineer,  the  skills  and  fundamental  information  related  to  industrial  chemistry are essential for understanding the parameters which control chemical  processes such as  Halogenation, Oxidation,  Isomerisation,   Nitration,  Pyrolysis,  Hydrogenation,    Hydrohalogenation,  Ozonolysis,  Polymerization,  Sulphonation,  Alkylation, Acetylation, Esterification, Dehydration, Phase rule, Adsorption, etc.  Production of synthetic materials like fertilizers, pesticides, dyes, drugs, plastics,  cosmetics,  etc.  used  by  human  beings  is  harmful  to  living  beings  and  pollutes  environment.  For  this,  presently,  scientists  are  trying  to  develop  methods  to  produce environmentally favourable chemical synthesis by Green Chemistry and  judicious use of them. India is a rising player in the global semiconductor industry  and  will  explore  to  grow  semiconductor  ecosystem.  There  will  be  a  futuristic  development of a sustainable semiconductor in industries. | Industrial Chemistry deals with the transformation of raw materials into required  products  that  are  beneficial  to  humanity  using  physical  and  chemical  processes  and fundamental principles of chemistry.   In chemical industries, during processes various organic compounds are used. The  knowledge  of  physical  and  chemical  properties  of  these  compounds  helps  the  diploma engineers how to use and control processes effectively. Therefore, for a  diploma  engineer,  the  skills  and  fundamental  information  related  to  industrial  chemistry are essential for understanding the parameters which control chemical  processes such as  Halogenation, Oxidation,  Isomerisation,   Nitration,  Pyrolysis,  Hydrogenation,    Hydrohalogenation,  Ozonolysis,  Polymerization,  Sulphonation,  Alkylation, Acetylation, Esterification, Dehydration, Phase rule, Adsorption, etc.  Production of synthetic materials like fertilizers, pesticides, dyes, drugs, plastics,  cosmetics,  etc.  used  by  human  beings  is  harmful  to  living  beings  and  pollutes  environment.  For  this,  presently,  scientists  are  trying  to  develop  methods  to  produce environmentally favourable chemical synthesis by Green Chemistry and  judicious use of them. India is a rising player in the global semiconductor industry  and  will  explore  to  grow  semiconductor  ecosystem.  There  will  be  a  futuristic  development of a sustainable semiconductor in industries. | Industrial Chemistry deals with the transformation of raw materials into required  products  that  are  beneficial  to  humanity  using  physical  and  chemical  processes  and fundamental principles of chemistry.   In chemical industries, during processes various organic compounds are used. The  knowledge  of  physical  and  chemical  properties  of  these  compounds  helps  the  diploma engineers how to use and control processes effectively. Therefore, for a  diploma  engineer,  the  skills  and  fundamental  information  related  to  industrial  chemistry are essential for understanding the parameters which control chemical  processes such as  Halogenation, Oxidation,  Isomerisation,   Nitration,  Pyrolysis,  Hydrogenation,    Hydrohalogenation,  Ozonolysis,  Polymerization,  Sulphonation,  Alkylation, Acetylation, Esterification, Dehydration, Phase rule, Adsorption, etc.  Production of synthetic materials like fertilizers, pesticides, dyes, drugs, plastics,  cosmetics,  etc.  used  by  human  beings  is  harmful  to  living  beings  and  pollutes  environment.  For  this,  presently,  scientists  are  trying  to  develop  methods  to  produce environmentally favourable chemical synthesis by Green Chemistry and  judicious use of them. India is a rising player in the global semiconductor industry  and  will  explore  to  grow  semiconductor  ecosystem.  There  will  be  a  futuristic  development of a sustainable semiconductor in industries. | Industrial Chemistry deals with the transformation of raw materials into required  products  that  are  beneficial  to  humanity  using  physical  and  chemical  processes  and fundamental principles of chemistry.   In chemical industries, during processes various organic compounds are used. The  knowledge  of  physical  and  chemical  properties  of  these  compounds  helps  the  diploma engineers how to use and control processes effectively. Therefore, for a  diploma  engineer,  the  skills  and  fundamental  information  related  to  industrial  chemistry are essential for understanding the parameters which control chemical  processes such as  Halogenation, Oxidation,  Isomerisation,   Nitration,  Pyrolysis,  Hydrogenation,    Hydrohalogenation,  Ozonolysis,  Polymerization,  Sulphonation,  Alkylation, Acetylation, Esterification, Dehydration, Phase rule, Adsorption, etc.  Production of synthetic materials like fertilizers, pesticides, dyes, drugs, plastics,  cosmetics,  etc.  used  by  human  beings  is  harmful  to  living  beings  and  pollutes  environment.  For  this,  presently,  scientists  are  trying  to  develop  methods  to  produce environmentally favourable chemical synthesis by Green Chemistry and  judicious use of them. India is a rising player in the global semiconductor industry  and  will  explore  to  grow  semiconductor  ecosystem.  There  will  be  a  futuristic  development of a sustainable semiconductor in industries. | Industrial Chemistry deals with the transformation of raw materials into required  products  that  are  beneficial  to  humanity  using  physical  and  chemical  processes  and fundamental principles of chemistry.   In chemical industries, during processes various organic compounds are used. The  knowledge  of  physical  and  chemical  properties  of  these  compounds  helps  the  diploma engineers how to use and control processes effectively. Therefore, for a  diploma  engineer,  the  skills  and  fundamental  information  related  to  industrial  chemistry are essential for understanding the parameters which control chemical  processes such as  Halogenation, Oxidation,  Isomerisation,   Nitration,  Pyrolysis,  Hydrogenation,    Hydrohalogenation,  Ozonolysis,  Polymerization,  Sulphonation,  Alkylation, Acetylation, Esterification, Dehydration, Phase rule, Adsorption, etc.  Production of synthetic materials like fertilizers, pesticides, dyes, drugs, plastics,  cosmetics,  etc.  used  by  human  beings  is  harmful  to  living  beings  and  pollutes  environment.  For  this,  presently,  scientists  are  trying  to  develop  methods  to  produce environmentally favourable chemical synthesis by Green Chemistry and  judicious use of them. India is a rising player in the global semiconductor industry  and  will  explore  to  grow  semiconductor  ecosystem.  There  will  be  a  futuristic  development of a sustainable semiconductor in industries. | Industrial Chemistry deals with the transformation of raw materials into required  products  that  are  beneficial  to  humanity  using  physical  and  chemical  processes  and fundamental principles of chemistry.   In chemical industries, during processes various organic compounds are used. The  knowledge  of  physical  and  chemical  properties  of  these  compounds  helps  the  diploma engineers how to use and control processes effectively. Therefore, for a  diploma  engineer,  the  skills  and  fundamental  information  related  to  industrial  chemistry are essential for understanding the parameters which control chemical  processes such as  Halogenation, Oxidation,  Isomerisation,   Nitration,  Pyrolysis,  Hydrogenation,    Hydrohalogenation,  Ozonolysis,  Polymerization,  Sulphonation,  Alkylation, Acetylation, Esterification, Dehydration, Phase rule, Adsorption, etc.  Production of synthetic materials like fertilizers, pesticides, dyes, drugs, plastics,  cosmetics,  etc.  used  by  human  beings  is  harmful  to  living  beings  and  pollutes  environment.  For  this,  presently,  scientists  are  trying  to  develop  methods  to  produce environmentally favourable chemical synthesis by Green Chemistry and  judicious use of them. India is a rising player in the global semiconductor industry  and  will  explore  to  grow  semiconductor  ecosystem.  There  will  be  a  futuristic  development of a sustainable semiconductor in industries. | Industrial Chemistry deals with the transformation of raw materials into required  products  that  are  beneficial  to  humanity  using  physical  and  chemical  processes  and fundamental principles of chemistry.   In chemical industries, during processes various organic compounds are used. The  knowledge  of  physical  and  chemical  properties  of  these  compounds  helps  the  diploma engineers how to use and control processes effectively. Therefore, for a  diploma  engineer,  the  skills  and  fundamental  information  related  to  industrial  chemistry are essential for understanding the parameters which control chemical  processes such as  Halogenation, Oxidation,  Isomerisation,   Nitration,  Pyrolysis,  Hydrogenation,    Hydrohalogenation,  Ozonolysis,  Polymerization,  Sulphonation,  Alkylation, Acetylation, Esterification, Dehydration, Phase rule, Adsorption, etc.  Production of synthetic materials like fertilizers, pesticides, dyes, drugs, plastics,  cosmetics,  etc.  used  by  human  beings  is  harmful  to  living  beings  and  pollutes  environment.  For  this,  presently,  scientists  are  trying  to  develop  methods  to  produce environmentally favourable chemical synthesis by Green Chemistry and  judicious use of them. India is a rising player in the global semiconductor industry  and  will  explore  to  grow  semiconductor  ecosystem.  There  will  be  a  futuristic  development of a sustainable semiconductor in industries. |

## Course Outcome:

After Completion of the Course, Student will able to:

|   No | Course Outcomes                                                                                                   | RBT Level   |
|------|-------------------------------------------------------------------------------------------------------------------|-------------|
|   01 | Solve  various engineering problems applying the concepts of organic compounds  on the basis of their properties. | R/U/A       |

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## GUJARAT TECHNOLOGICAL UNIVERSITY

## Program Name: Diploma in Engineering

## Level: Diploma

## Branch: Chemical Engineering

Course / Subject Code : DI02000031

Course / Subject Name  : Industrial Chemistry

|   02 | Use  relevant aliphatic and aromatic compounds to solve domestic and industrial  applications.                                                                                                         | R/U/A   |
|------|--------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------|---------|
|   03 | Illustrate  the principles of one component system using phase rule for industrial  applications.                                                                                                      | R/U/A   |
|   04 | Apply   different  adsorption  phenomena  and  its  isotherms  for  domestic  and  industrial applications.                                                                                            | R/U/A   |
|   05 | Solve the  engineering  problems  using  eco-friendly  chemicals  &  synthesis  methods  using  the  principles  of  green  chemistry  and  semiconductors  for  domestic and industrial applications. | R/U/A   |

*Revised Bloom's Taxonomy (RBT)

## Teaching and Examination Scheme:

| Teaching Scheme  (in Hours)   | Teaching Scheme  (in Hours)   | Teaching Scheme  (in Hours)   | Total  Credits  L+T+  (PR/2)   | Assessment Pattern and Marks   | Assessment Pattern and Marks   | Assessment Pattern and Marks   | Assessment Pattern and Marks   | Total   |
|-------------------------------|-------------------------------|-------------------------------|--------------------------------|--------------------------------|--------------------------------|--------------------------------|--------------------------------|---------|
| L                             |                               | PR                            | C                              | Theory                         | Theory                         | Tutorial / Practical           | Tutorial / Practical           | Marks   |
|                               | T                             |                               |                                | ESE (E)                        | PA /  CA (M)                   | PA/CA (I)                      | ESE (V)                        |         |
| 3                             | 0                             | 2                             | 4                              | 70                             | 30                             | 20                             | 30                             | 150     |

## Course Content:

|   Unit  No. | Content                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                  |   No. of  Hours | % of  Weightage   |
|-------------|----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------|-----------------|-------------------|
|           1 | Concepts of Organic Chemistry  1.1 The  IUPAC  System  of  Nomenclature  of  Organic  Compounds  having Functional Groups and simple Substituent groups.  1.2 Alkanes: Reactivity  of  Alkanes  (1 o ,  2 o ,  3 o ),  Methods  of  Preparation,  Physical  Properties,  Chemical  Properties  (Halogenation,  Controlled  Oxidation,  Isomerisation,  Nitration,  Pyrolysis) and Uses.  1.3 Cycloalkanes:  Methods of Preparation, Properties (Halogenation,  Oxidation) and Uses.    1.4 Alkenes:   Methods  of  Preparation,  Physical  Properties,  Chemical  Properties  (Addition  reactions  with  -  Dihydrogen  (Hydrogenation),  Halogen  (Halogenation),  Hydrogen  halide  (Hydrohalogenation  -  Markovniknov's  rule),  Sulphuric  acid;  Oxidation, Ozonolysis, Polymerization) and Uses. |              12 | 29%  (20 Marks)   |

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## GUJARAT TECHNOLOGICAL UNIVERSITY

## Program Name: Diploma in Engineering Level: Diploma Branch: Chemical Engineering Course / Subject Code : DI02000031

Course / Subject Name  : Industrial Chemistry

|    | 1.5 Alkynes:   Methods  of  Preparation,  Physical  Properties,  Chemical  Properties  (Addition  reactions  with  -  Dihydrogen  (Hydrogenation),  Halogen  (Halogenation);  Polymerization)  and                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                            |    |                 |
|----|-------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------|----|-----------------|
|  2 | Uses.  Aromatic (Arenes) and Aliphatic Compounds  2.1. Benzene:   Structure  of  Benzene  based  on  Chemical  properties,  Structure  of  Benzene  based  on  Physical  Properties,  Methods  of  Preparation,  Physical Properties, Chemical Properties (Nitration, Sulphonation,  Chlorination,  Bromination,  Alkylation,  Acetylation,  Hydrogenation, Pyrolysis) and Uses.  2.2. Huckel's  rule  with  examples,  Concept  of  Aromaticity/Aromatic  characteristics.  2.3. Alkyl halides/Halo alkanes (R-X):   Definition, Classification (on the basis of no. of halogen atoms, on  the basis of no. of carbon atoms attached to Csp3-X), Methods of  Preparation,  Chemical  Properties  (Nucleophilic  Substitution  reactions (SN2 & SN1) and Elimination reactions) and Uses.  2.4. Alcohols (R-OH):   Definition, Classification (on the basis of no. of -OH groups, on  the basis of no. of carbon atoms attached to Csp3-OH), Methods of  Preparation  (Methanol,  Ethanol),  Physical  Properties,  Chemical  Properties  (Reaction  with  Sodium,  Oxidation,  Esterification,  Dehydration) and Uses.  2.5. Phenol:   Definition, Methods of Preparation, Physical Properties, Chemical  Properties (Nitration, Halogenation, Kolbe reaction, Reaction with | 12 | 26%  (18 Marks) |
|  3 | Phase Rule  3.1. Phase Rule.   3.2. Phase, No. of Phases (P).   3.3. Components, No. of Components (C).   3.4. Degrees of Freedom, No. of degree of freedom (F).  3.5. Phase Diagrams and its Uses.   3.6. Phase Rule for One Component Systems - Water Systems.  3.7. Applications/Merits of Phase Rule.   3.8. Limitations of Phase Rule.                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                   |  6 | 14%  (10 Marks) |
|  4 | Adsorption and Solutions  Adsorption:                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                         |  7 | 14%  (10 Marks) |

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## GUJARAT TECHNOLOGICAL UNIVERSITY

## Program Name: Diploma in Engineering

## Level: Diploma

## Branch: Chemical Engineering

Course / Subject Code : DI02000031

Course / Subject Name  : Industrial Chemistry

|    | 4.1. Adsorption  and  Absorption,  Desorption,  Sorption  with  suitable  examples.   4.2. Differences between Adsorption and Absorption.   4.3. Types of Adsorption - Physical adsorption, Chemical adsorption.  4.4. Factors influencing Adsorption.   4.5. Adsorption Isotherms - Freundlich adsorption isotherm, Langmuir  adsorption isotherm.  4.6. Applications of Adsorption.  Solutions:  4.7. Solutions and Indicators.  4.8. Raoult's Law for a non-volatile solution.  4.9. Ideal solutions and Non-ideal solutions.                                                                                                                                                                                                                                                                                                                                                                                                                                                                              |    |                   |
|----|---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------|----|-------------------|
| 5. | 4.10. Azeotropic mixture/Azeotropes.  Green Chemistry and Semiconductors  Green Chemistry: 5.1. Concept of Green Chemistry.  5.2. Basic Principles of Green Chemistry.  5.3. Examples  of  Green  Synthesis  -  Synthesis  of  Adipic  acid  from   Cyclohexene, Synthesis of soluble Polyphenol.  5.4. Advantages of Green Chemistry.    5.5. Green Chemistry in Day-to-day life: In Dry-cleaning of Clothes,  In  bleaching  of  paper,  Synthesis  of  Chemicals  (Ethanal  from  Ethene), 'Green Solution' to Clean Turbid Water.  5.6. Applications of Green Chemistry in Industries.  Semiconductors: 5.7. Definition and Properties of Semiconductors.  5.8. Types/Classification of Semiconductors:  1. Elemental Semiconductors:  Intrinsic  Semiconductors,  Extrinsic  Semiconductors  (n-type  extrinsic semiconductors, p-type extrinsic semiconductors).  2. Non-elemental/Compound Semiconductors:  Inorganic  semiconductors,  Organic  semiconductors  and  Semiconducting Organic Polymers. |  8 | 17%  (12 Marks)   |
|    | Total                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                         | 45 | 100%  (70  Marks) |

Suggested Specification Table with Marks (Theory):

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## GUJARAT TECHNOLOGICAL UNIVERSITY

## Program Name: Diploma in Engineering

## Level: Diploma

## Branch: Chemical Engineering

Course / Subject Code : DI02000031

Course / Subject Name  : Industrial Chemistry

## Distribution of Theory Marks (in %)

| R Level          | U Level          | A Level          | N Level   | E Level   | C Level   |
|------------------|------------------|------------------|-----------|-----------|-----------|
| 24 Marks  (35 %) | 32 Marks  ( 45%) | 14 Marks  (20 %) | -         | -         | -         |

Where R: Remember; U: Understanding; A: Application, N: Analyze and E: Evaluate C: Create (as per Revised Bloom's Taxonomy)

Note : This specification table provides general guidelines to assist students for their learning and to teachers to teach and question paper designers/setters to formulate test items/questions to assess the attainment of the UOs. The actual distribution of marks at different taxonomy levels (of R, U and A) in the question paper may slightly vary from above table.

## References/Suggested Learning Resources:

## (a) Books:

|   Sr.  No. | Title of Book                                                            | Author                                 | Publication with place, year and ISBN                                                                                                                                  |
|------------|--------------------------------------------------------------------------|----------------------------------------|------------------------------------------------------------------------------------------------------------------------------------------------------------------------|
|          1 | Textbook  of  Organic  Chemistry                                         | Rakesh  K.  Parashar,  V. K. Ahluwalia | Viva Books Private Limited, New Delhi,  2012,  ISBN: 9788130917740                                                                                                     |
|          2 | A  Textbook  of  Organic  Chemistry                                      | Bahl  Arun,  Bahl  B.  S.              | S. Chand & Company Ltd., New Delhi,   2016,   ISBN: 9352531965                                                                                                         |
|          3 | Organic Chemistry  Volume 1: The Fundamental  Principles (6 th  Edition) | I. L. Finar                            | ELBS, Singapore,  ISBN: 058240746 X                                                                                                                                    |
|          4 | Text Book of Chemistry for  Class XI & XII (Part - I, Part  - II)        | NCERT                                  | NCERT, New Delhi, 2017-18, Class XI,  ISBN: 81-7450-494-X (part-I), 81-7450- 535-O  (part-II),  Class-XII,  ISBN:  81- 7450-648-9  (part-I),  81-7450-716-7  (part-II) |
|          5 | Advanced  Physical  Chemistry Book                                       | D. N. Bajpal                           | S.  Chand Publishing, 2001, New Delhi,  2001,  ISBN: 8121904080                                                                                                        |
|          6 | Engineering Chemistry                                                    | P. C. Jain & Monica  Jain              | Dhanpat  Rai  and  Sons  Publishing  Company  (P)  Ltd.,  New  Delhi,  2015,  ISBN: 8187433175                                                                         |

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## GUJARAT TECHNOLOGICAL UNIVERSITY

## Program Name: Diploma in Engineering

## Level: Diploma

## Branch: Chemical Engineering

Course / Subject Code : DI02000031

Course / Subject Name  : Industrial Chemistry

10

| Sr.  No.   | Title of Book                                                       | Author                                                 | Publication with place, year and ISBN                                   |
|------------|---------------------------------------------------------------------|--------------------------------------------------------|-------------------------------------------------------------------------|
| 7          | Principles  of  Physical  Chemistry                                 | B.  R.  Puri,  L.  R.  Sharma  and  Madan  S. Pathania | Shoban  Lal  Nagin  Chand  &  Co.,  Jalandhar, 1989.                    |
| 8          | Vogel's  Textbook  of  Practical Organic Chemistry  (4 th  Edition) | Furniss,  Hannaford,  Rogers,  Smith,  Tatchell        | ELBS, Singapore,  ISBN: 0582002478                                      |
| 9          | Handbook  of  Green  Chemistry and Technology                       | Clark James                                            | Wiley India Pvt. Ltd, New Delhi,   ISBN: 9788126548002                  |
|            | Green Chemistry                                                     | V. K. Ahluwalia                                        | Narosa Publishing House Pvt. Ltd., New  Delhi, 2012,   ISBN: 8184872011 |

## (b) Open source software and website:

1. https://ndl.iitkgp.ac.in
2. https://vlab.amrita.edu/index.php?sub=2&amp;brch=190
3. www.vlab.co.in
4. http://www.olabs.edu.in/
5. www.chemistry.msu.edu
6. https://www.chemistry-teaching-resources.com/
7. https://www.asdlib.org/onlineArticles/ecourseware/Manahan/GreenChem-2.pdf
8. https://www.mygreenlab.org/uploads/2/1/9/4/21945752/green\_chemistry\_principles\_and\_lab\_p ractices\_2.0.pdf
9. https://ncert.nic.in/textbook/pdf/leph206.pdf

## Suggested Course Practical List:

|   Sr.  No. | Practical Outcomes (PrOs)                                                                                                                 | Unit  No.   |
|------------|-------------------------------------------------------------------------------------------------------------------------------------------|-------------|
|          1 | Identify the functional group (Carboxylic acid, Alcohol, Ketone,  Aldehyde) present in given organic compound.                            | 1           |
|          2 | Perform tests for saturation and unsaturation using Br2 water and  Baeyer's (KMnO4) solution of given aliphatic compound.                 | 1           |
|          3 | Determine aliphatic/aromatic nature of given organic compounds.                                                                           | 2           |
|          4 | Determine the nature (acidic, phenolic, basic, neutral) of the given  organic  compound  by  preliminary  tests  of  organic  qualitative | 1, 2        |

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## GUJARAT TECHNOLOGICAL UNIVERSITY

## Program Name: Diploma in Engineering

## Level: Diploma

## Branch: Chemical Engineering

Course / Subject Code : DI02000031

Course / Subject Name  : Industrial Chemistry

| Sr.  No.   | Practical Outcomes (PrOs)                                                                                              | Unit  No.   |
|------------|------------------------------------------------------------------------------------------------------------------------|-------------|
|            | analysis.                                                                                                              |             |
| 5.         | Identify  the  given  organic  compound  (Acetic  acid,  Oxalic  acid,  Benzoic acid) by organic qualitative analysis. | 1, 2        |
| 6.         | Identify the given organic compound (Aniline, N-methyl aniline)  by organic qualitative analysis.                      | 1, 2        |
| 7.         | Identify 1 o , 2 o , 3 o  alcohols by Lucas Test.                                                                      | 2           |
| 8.         | Identify  the  given  alcohol  (Methanol,  Ethanol)  by  organic  qualitative analysis.                                | 2           |
| 9.         | Determine the given alcohol using qualitative analysis.                                                                | 2           |
| 10.        | Determine the given aldehyde using qualitative analysis.                                                               | 2           |
| 11.        | Identify  the  given  aromatic  carboxylic  acid  using  qualitative  analysis.                                        | 2           |
| 12.        | Identify the given aromatic amine using qualitative analysis.                                                          | 2           |
| 13.        | Identify  the  given  organic  compound  (Phenol,  Catechol,  Resorcinol, Quinol) by organic qualitative analysis.     | 2           |
| 14.        | Purify raw (brown) sugar using activated charcoal.                                                                     | 4           |
| 15.        | Determine  the  adsorption  isotherm  of  acetic  acid  by  activated  charcoal.                                       | 4           |
| 16.        | Determine boiling point of azeotropic mixture.                                                                         | 4           |
| 17.        | Synthesize p-methoxy chalcone by grinding method.                                                                      | 5           |

## Note:

- i. Practical Exercises of at least 30 Hrs . should be completed by the end of the term.
- ii. More Practical  Exercises can  be  designed  and  offered  by  the  respective  course  teacher  to develop  the  industry-relevant  skills/outcomes  to  match  the  COs.  The  above  table  is  only  a suggestive list.
- iii. The  following  are  some sample  'Process' and 'Product'  related  skills (more  may  be added/deleted depending on the course) that occur in the above listed Practical Exercises of this course required which are embedded in the COs and ultimately the competency.

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## GUJARAT TECHNOLOGICAL UNIVERSITY

## Program Name: Diploma in Engineering

## Level: Diploma

## Branch: Chemical Engineering

Course / Subject Code : DI02000031

Course / Subject Name  : Industrial Chemistry

| Sr. No.   | Sample Performance Indicators for the PrOs                                                                  | Weightage in  %          | Maximum  Marks for  PA/CA (I)   |
|-----------|-------------------------------------------------------------------------------------------------------------|--------------------------|---------------------------------|
|          | 'Process' related skills                                                                                    | 'Process' related skills | 'Process' related skills        |
| 1.        |   Prepare experimental setup accurately.   Handling  of  apparatus/glassware  for  precise  measurements. | 20                       | 4                               |
| 2.        |   Practice and adapt good and safe measuring techniques.     Record observations correctly.               | 20                       | 4                               |
| 3.        |   Housekeeping.    Observance /Follow safety rules.                                                       | 20                       | 4                               |
|          | 'Product' related skills                                                                                    | 'Product' related skills | 'Product' related skills        |
| 4.        |   Does Calculations. (if any)    Interpret the Results and their Conclusion/s.                            | 20                       | 4                               |
| 5.        |   Prepare report of practical in prescribed format.    Viva-voce.                                         | 20                       | 4                               |
| Total     | Total                                                                                                       | 100                      | 20                              |

|   Sr. No. | Name of Equipments / Instruments                                                | Practical No.   |
|-----------|---------------------------------------------------------------------------------|-----------------|
|         1 | Electronic Weighing Balance / Digital Weighing Balance (OR Analytical  Balance) | 10, 11,13,15    |
|         2 | Hot Plate with Magnetic Stirrer                                                 | 10, 11, 12,13   |

## List of Laboratory/Learning Resources Required:

- a) https://ndl.iitkgp.ac.in
- b) https://vlab.amrita.edu/index.php?sub=2&amp;brch=190
- c) www.vlab.co.in
- d) http://www.olabs.edu.in/
- e) www.chemistry.msu.edu
- f) https://www.chemistry-teaching-resources.com/
- g) https://www.asdlib.org/onlineArticles/ecourseware/Manahan/GreenChem-2.pdf
- h) https://www.mygreenlab.org/uploads/2/1/9/4/21945752/green\_chemistry\_principles\_and\_lab\_p ractices\_2.0.pdf
- i) https://www.ikbooks.com/home/samplechapter?filename=195\_Sample-Chapter.pdf

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## GUJARAT TECHNOLOGICAL UNIVERSITY

## Program Name: Diploma in Engineering

## Level: Diploma

## Branch: Chemical Engineering

Course / Subject Code : DI02000031

Course / Subject Name  : Industrial Chemistry

## Suggested Project List:

- a) Organic compounds: Prepare a chart for classification of organic compounds.
- b) IUPAC Nomenclature: Prepare a PowerPoint presentation or animation that can explain the IUPAC nomenclature system.
- c) Aliphatic  hydrocarbons: Prepare  molecular  models  of  alkanes,  alkenes  and  alkynes  to demonstrate the structures.
- d) Aromatic characteristics of Benzene: Prepare a chart/poster showing aromatic characteristics of Benzene.
- e) Standard  methods  used  in  Industries: Make  a  list  of  standard  methods  used  to  prepare different aliphatic and aromatic compounds in industries.
- f) Terms of Phase rule : Prepare a chart or PowerPoint presentation showing calculation of the number of phases, components and degrees of freedom in different systems.
- g) Adsorption : Collect different types of adsorbates and adsorbents. Observe adsorption process in relevant materials and prepare report based on observations.
- h) Eco-friendly Indicators: Prepare eco-friendly acid-base indicators by extraction from flowers and vegetables. Also demonstrate it by chart/poster/PowerPoint presentation.
- i) Use of Chemicals in Day-to-day Life: Prepare a chart/poster on chemicals which are used in day-to-day life - their names, structures, physical and chemical properties and uses.
- j) Green Synthesis: Prepare a list of green synthesis of organic renewable raw materials used in industries. Discuss the findings with your teacher and classmates.
- k) Green Chemistry: Compile report of green synthesis methods used in industries. Discuss the findings with your teacher and classmates.
- l) Semiconductors: Classify  Semiconductors  with  examples.  Enlist  Semiconductor  Devices. Also collect Semiconductors.

## Suggested Activities for Students:

- a) Prepare tabular classification of functional groups with examples.
- b) Prepare chart on IUPAC nomenclature of organic compounds.
- c) Prepare table of organic compounds  of relevant topics with structure and industrial applications.
- d) Library survey of different aliphatic hydrocarbons used in industries.
- e) Library survey of different aromatic hydrocarbons used in industries.
- f) Prepare a table showing the difference between aliphatic and aromatic compounds.
- g) Market  survey  of  different  aliphatic  and  aromatic  compounds,  and  differentiate  by  their physical and chemical properties.

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## GUJARAT TECHNOLOGICAL UNIVERSITY

## Program Name: Diploma in Engineering

## Level: Diploma

## Branch: Chemical Engineering

Course / Subject Code : DI02000031

Course / Subject Name  : Industrial Chemistry

- h) Prepare  a  category-wise  list  of  all  compounds  with  their  IUPAC  names/common  names  and structural formulae covered in the syllabus.
- i) Make a list  of  all  probable  organic  conversions  with  their  reaction-equations  covered  in  the syllabus.
- j) Make a chart showing examples of different terms of phase rule.
- k) Collect different adsorbates and adsorbents and make a chart based on their type, properties, and uses. Also write examples illustrating absorption, adsorption, desorption and sorption.
- l) Make  a  chart  showing  differences  between  Freundlich  adsorption  isotherm  and  Langmuir adsorption isotherm.
- m) Give seminar on any relevant topic.
- n) Prepare a PowerPoint presentation or animation for the given topic.
- o) Identify  green  synthesis  of  various  intermediates  and  renewable  raw  materials  of  organic compounds used in industries.

* * * * * * *