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## GUJARAT TECHNOLOGICAL UNIVERSITY

Program Name: Diploma in Engineering Level: Diploma

Branch: Sem-1:Chemical Engineering/Textile Processing Technology

Sem-2 :Instrumentation &amp; Control/Textile Manufacturing/

Automation &amp; Robotics/Printing Technology

Course / Subject Code: DI01000161

Course / Subject Name:  Basic Chemistry

w. e. f. Academic Year:

2024-25

Semester:

1 or 2

Category of the Course:

Basic Science Courses (BSC)

Prerequisite:

Fundamental knowledge of Chemistry and basic Arithmetic for simple calculations.

Rationale:

The  branch  of  applied  science  which  deals  with  chemistry  is  known  as  Basic chemistry. The study of concepts and principles of Basic chemistry will aid the technicians in  comprehending and solving  engineering problems. Thus,  a strong foundation in applied science will help the students in their self-development to cope  up  with  the  constant  influx  of  innovations.  There  are  numerous  materials used  in  fabricating  and  manufacturing  devices  for  the  comfort  of  life.  The selection,  characterization,  and  suitability  assessment  of  natural  raw  materials essentially  requires  principles  and  concepts  of  Basic  Chemistry  for  technicians. Successful completion of this course content will enable technicians to understand, ascertain and analyze properties of natural raw materials required for producing economical and eco-friendly finished products through the inclusion of various creative activities/projects etc. Many global problems/issues and their indepth understanding is addressed through the inclusion of topics of relevance like atomic  structure,  chemical  bonding  and  solutions;  electrochemistry;  corrosion; water treatment; lubricants; polymers, elastomers, adhesives and semiconductors in this course.

## Course Outcome:

After Completion of the Course, Student will able to:

|   No. | Course Outcomes                                                                                                             | RBT Level   |
|-------|-----------------------------------------------------------------------------------------------------------------------------|-------------|
|    01 | Apply   the  principles  of  atomic  structure,  chemical  bonding  and  solutions  to  solve various engineering problems. | R/U/A       |
|    02 | Solve engineering  problems  using  the  concepts  of  electrochemistry  and  corrosion.                                    | R/U/A       |
|    03 | Use relevant  water  treatment  methods  to  solve  domestic  and  industrial  problems.                                    | R/U/A       |

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## GUJARAT TECHNOLOGICAL UNIVERSITY

## Program Name: Diploma in Engineering

Level: Diploma

Branch: Sem-1:Chemical Engineering/Textile Processing Technology

Sem-2 :Instrumentation &amp; Control/Textile Manufacturing/

Automation &amp; Robotics/Printing Technology

Course / Subject Code: DI01000161

Course / Subject Name:  Basic Chemistry

|   04 | Classify  organic compounds based on their functional groups.                                                                                                                 | R/U/A   |
|------|-------------------------------------------------------------------------------------------------------------------------------------------------------------------------------|---------|
|   05 | Choose   various  types  of  engineering  materials  like  lubricants,  polymers,  elastomers,  adhesives  and  semiconductors  for  domestic  and  industrial  applications. | R/U/A   |

*Revised Bloom's Taxonomy (RBT)

## Teaching and Examination Scheme:

| Teaching Scheme  (in Hours)   | Teaching Scheme  (in Hours)   | Teaching Scheme  (in Hours)   | Total  Credits  L+T+  (PR/2)   | Assessment Pattern and Marks   | Assessment Pattern and Marks   | Assessment Pattern and Marks   | Assessment Pattern and Marks   | Total   |
|-------------------------------|-------------------------------|-------------------------------|--------------------------------|--------------------------------|--------------------------------|--------------------------------|--------------------------------|---------|
| L                             | T                             | PR                            | C                              | Theory                         | Theory                         | Tutorial / Practical           | Tutorial / Practical           | Marks   |
|                               |                               |                               |                                | ESE  (E)                       | PA/CA  (M)                     | PA/CA (I)                      | ESE  (V)                       |         |
| 3                             | 0                             | 2                             | 4                              | 70                             | 30                             | 20                             | 30                             | 150     |

## Course Content:

|   Unit  No. | Content                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                     |   No. of  Hours | % of  Weightage   |
|-------------|---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------|-----------------|-------------------|
|           1 | Atomic Structure, Chemical Bonding and Solutions  Atomic Structure: 1.1. Concepts of orbits and orbitals.   1.2. Pauli's  exclusion  principle,  Hund's  rule  of  maximum  spin  multiplicity, Aufbau rule.  1.3. Electronic configuration of elements having atomic number 1  to 30.  Chemical Bonding: 1.4. Concept of chemical bond, Octet rule,   Types of chemical bonds :    1.4.1  Ionic (Electrovalent) bond and its characteristics   (Example NaCl.),   1.4.2  Covalent bond and its characteristics   (examples-Non-polar covalent bond: H2, O2, N2, CH4;   Polar covalent bond: HCl, H2O, And NH3.),   1.4.3  Coordinate covalent (Dative) bond   (examples - NH4 + , H3O + ), |              08 | 17%  (12 Marks)   |

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## GUJARAT TECHNOLOGICAL UNIVERSITY

Program Name: Diploma in Engineering Level: Diploma

Branch: Sem-1:Chemical Engineering/Textile Processing Technology

Sem-2 :Instrumentation &amp; Control/Textile Manufacturing/

Automation &amp; Robotics/Printing Technology

Course / Subject Code: DI01000161

Course / Subject Name:  Basic Chemistry

|    | 1.4.5  Hydrogen bond, its types and significance,   1.4.6  Intermolecular force of attraction (van der Waals bond).  1.5. Structures  of  solids:  Ionic  solids,  Molecular  solids,  Network  solids, and Metallic solids.  Definitions  of  solute,  solvent,  solution  and  concentration,  Modes of expressing concentration of solutions -   Molarity (M = mole/liter), Normality (N), Molality (m), mass   | 1.4.4  Metallic bond and its characteristics,                                                                                                                                                                        |    |            |
|----|--------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------|----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------|----|------------|
|    | Solutions:                                                                                                                                                                                                                                                                                                                                                                                                         | Solutions:                                                                                                                                                                                                           |    |            |
|    | 1.6.                                                                                                                                                                                                                                                                                                                                                                                                               | percentage  (%w/w),  volume  percentage  (%v/v),  mass  by  volume percentage (%w/v), mole fraction (  ), ppm (  g/mL).                                                                                            |    |            |
| 2. | Electrochemistry                                                                                                                                                                                                                                                                                                                                                                                                   | Electrochemistry                                                                                                                                                                                                     | 07 | 15%        |
|    | 2.1.                                                                                                                                                                                                                                                                                                                                                                                                               | Arrhenius theory of ionization.                                                                                                                                                                                      |    | (11 Marks) |
|    | 2.2.                                                                                                                                                                                                                                                                                                                                                                                                               | Electronic  concept  of  oxidation,  reduction,  and  redox  reactions.                                                                                                                                              |    |            |
|    | 2.3.                                                                                                                                                                                                                                                                                                                                                                                                               | Degree of ionization (  ) and the factors affecting on it.                                                                                                                                                          |    |            |
|    | 2.4.                                                                                                                                                                                                                                                                                                                                                                                                               | Concept of pH and pOH; pH scale for acids, bases and neutral  solutions,  Calculations  of  pH  and  pOH  for  acids  and  bases  solutions  of  different  concentrations,  Importance  of  pH  in  various fields. |    |            |
|    | 2.5.                                                                                                                                                                                                                                                                                                                                                                                                               | Buffer solutions, Types of buffer solutions: Acidic buffers and  Basic buffers, Applications of buffer solutions.                                                                                                    |    |            |
|    | 2.6.                                                                                                                                                                                                                                                                                                                                                                                                               | Definition  of  Electrolytes,  Non-electrolytes  with  suitable  examples, Types of Electrolytes with examples.                                                                                                      |    |            |
|    | 2.7.                                                                                                                                                                                                                                                                                                                                                                                                               | Construction,  working,  cell-reactions  and  symbolic  representation of an Electrochemical cell.                                                                                                                   |    |            |
|    | 2.8.                                                                                                                                                                                                                                                                                                                                                                                                               | Conditions for a half-cell to be standard.                                                                                                                                                                           |    |            |
|    | 2.9.                                                                                                                                                                                                                                                                                                                                                                                                               | Construction  and  working  of  Standard  Hydrogen  Electrode  (SHE).                                                                                                                                                |    |            |
|    | 2.10.                                                                                                                                                                                                                                                                                                                                                                                                              | Measurement  of  Standard  half-cell  potential  /  Standard  electrode  potential  (E o R  or  EoL),  Electrochemical/electromotive force (emf) series, Standard cell  potential (E o cell ).                       |    |            |
|    | 2.11.                                                                                                                                                                                                                                                                                                                                                                                                              | Construction of Electrolytic cell and Electrolysis.                                                                                                                                                                  |    |            |
|    | 2.12.                                                                                                                                                                                                                                                                                                                                                                                                              | Faraday's Laws of Electrolysis.                                                                                                                                                                                      |    |            |
|    | 2.13.                                                                                                                                                                                                                                                                                                                                                                                                              | Industrial applications of electrolysis:                                                                                                                                                                             |    |            |

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## GUJARAT TECHNOLOGICAL UNIVERSITY

Program Name: Diploma in Engineering Level: Diploma

Branch: Sem-1:Chemical Engineering/Textile Processing Technology Sem-2 :Instrumentation &amp; Control/Textile Manufacturing/ Automation &amp; Robotics/Printing Technology Course / Subject Code: DI01000161 Course / Subject Name:  Basic Chemistry

|    | 2.13.2 Electroplating,   2.13.3 Electro-refining.                                                                                                                                                                                                                                                                                                                                                                                                                                                                                      |    |                 |
|----|----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------|----|-----------------|
|  3 | Corrosion of metals and its prevention  3.1. Definition of Corrosion with example.                                                                                                                                                                                                                                                                                                                                                                                                                                                     | 05 | 12%  (8 Marks)  |
|  4 | Water treatment  4.1 Sources of water, hard water and Soft water.  4.2 Types of hardness of water (Temporary/Carbonate harness and  Permanent/Non-carbonate  hardness),  salts  causing  it  and  simple numericals based on it.  4.3 Units of hardness.  4.4 Problems  caused  by  the  use  of  hard  water  in  boilers  and  its  prevention:  4.4.1 Scale and sludge formation,   4.4.2 Priming and Foaming,   4.4.3 Caustic embrittlement,   4.4.4 Boiler Corrosion.  4.5 Water softening techniques:   4.5.1 Soda-lime process, | 07 | 14%  (10 Marks) |

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## GUJARAT TECHNOLOGICAL UNIVERSITY

Program Name: Diploma in Engineering Level: Diploma

Branch: Sem-1:Chemical Engineering/Textile Processing Technology

Sem-2 :Instrumentation &amp; Control/Textile Manufacturing/

Automation &amp; Robotics/Printing Technology

Course / Subject Code: DI01000161

Course / Subject Name:  Basic Chemistry

|    | 4.6 4.7                              | 4.5.4 Reverse Osmosis (R.O.) process.    Treatment of Municipal drinking water:   4.6.1 Screening,   4.6.2 Sedimentation,   4.6.3 Coagulation,   4.6.4 Filtration,   4.6.5 Sterilization  of  water  by  Chlorination,  Break-point  (Free-residual) Chlorination.  Enlist Indian standard specifications of drinking water.   |    |                |
|----|--------------------------------------|--------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------|----|----------------|
|  5 | Basic concepts of Organic Chemistry: | Basic concepts of Organic Chemistry:                                                                                                                                                                                                                                                                                           | 06 | 12%  (8 Marks) |
|  5 | 5.1                                  | Organic and Inorganic Compounds.                                                                                                                                                                                                                                                                                               | 06 | 12%  (8 Marks) |
|  5 | 5.2                                  | Tetravalency of Carbon.                                                                                                                                                                                                                                                                                                        | 06 | 12%  (8 Marks) |
|  5 | 5.3 5.4                              | Concept of Hybridization, Types of hybridization: sp, sp 2   and  sp 3  hybridization with examples.  Sigma bonding and Pi bonding.                                                                                                                                                                                            | 06 | 12%  (8 Marks) |
|  5 | 5.5                                  | Classification of Organic compounds, IUPAC nomenclature of                                                                                                                                                                                                                                                                     | 06 | 12%  (8 Marks) |
|  5 |                                      | simple hydrocarbons.                                                                                                                                                                                                                                                                                                           | 06 | 12%  (8 Marks) |
|  5 | 5.6 5.7                              | Functional groups and its classification.                                                                                                                                                                                                                                                                                      | 06 | 12%  (8 Marks) |
|  5 | 5.8                                  |                                                                                                                                                                                                                                                                                                                                | 06 | 12%  (8 Marks) |
|  5 |                                      | Isomerism and Homologous series.                                                                                                                                                                                                                                                                                               | 06 | 12%  (8 Marks) |
|  5 |                                      | Saturated Hydrocarbons and Unsaturated Hydrocarbons.                                                                                                                                                                                                                                                                           | 06 | 12%  (8 Marks) |
|  5 | 5.9                                  | Source  of  hydrocarbons:  Distillation  of  coal  tar,  Refining  of  petroleum.                                                                                                                                                                                                                                              | 06 | 12%  (8 Marks) |
|  5 | 5.10                                 | Preparation,  Properties  and  Uses  of  Alkane  (Ethane),  Alkene  (Ethene/Ethylene), Alkyne (Ethane/Acetylene).                                                                                                                                                                                                              | 06 | 12%  (8 Marks) |
|  6 | Lubricants                           | Lubricants                                                                                                                                                                                                                                                                                                                     | 04 | 10%  (7 Marks) |
|  6 | 6.1                                  | Lubricants and Lubrication, Functions of lubricants.                                                                                                                                                                                                                                                                           | 04 | 10%  (7 Marks) |
|  6 | 6.2 6.3                              | Mechanism  of  Lubrication:  Fluid  lubrication,  Boundary  lubrication.  Classification  of  lubricants  with  examples:  Solid,  Semi-solid, Liquid and Synthetic lubricants.                                                                                                                                                | 04 | 10%  (7 Marks) |
|  6 | 6.4                                  | Physical Properties of lubricants: Viscosity and Viscosity index,  Flash point and Fire point, Cloud point and Pour point, Oiliness.                                                                                                                                                                                           | 04 | 10%  (7 Marks) |
|  6 | 6.5                                  | Chemical  properties  of  lubricants:  Saponification  number,  Neutralization number, Emulsification number.                                                                                                                                                                                                                  | 04 | 10%  (7 Marks) |
|  6 | 6.6                                  |                                                                                                                                                                                                                                                                                                                                | 04 | 10%  (7 Marks) |
|  6 |                                      | Selection  of  lubricants  for  different  types  of  Machinery  like:  Gears, Cutting tools, Steam turbine, Transformers.                                                                                                                                                                                                     | 04 | 10%  (7 Marks) |

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## GUJARAT TECHNOLOGICAL UNIVERSITY

Program Name: Diploma in Engineering Level: Diploma

Branch: Sem-1:Chemical Engineering/Textile Processing Technology Sem-2 :Instrumentation &amp; Control/Textile Manufacturing/ Automation &amp; Robotics/Printing Technology Course / Subject Code: DI01000161

Course / Subject Name:  Basic Chemistry

|    | 6.7                                                          | Biodegradable lubricants.                                                                                                                                                                                                                                                                                        |    |                 |
|----|--------------------------------------------------------------|------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------|----|-----------------|
| 7. | Polymers, Elastomers, Adhesives and Semiconductors Polymers: | Polymers, Elastomers, Adhesives and Semiconductors Polymers:                                                                                                                                                                                                                                                     | 08 | 20%  (14 Marks) |
|    | 7.1                                                          | Definition  of  Monomer,  Polymer,  Polymerization,  Degree  of  polymerization (n) and Repeating unit.                                                                                                                                                                                                          |    |                 |
|    | 7.2                                                          | Classification of polymers based on Molecular structure:     Linear polymers, Branched polymers, Cross-linked polymers.                                                                                                                                                                                          |    |                 |
|    | 7.3                                                          | Classification of polymers based on Monomer:   Homo polymer, Co-polymer.                                                                                                                                                                                                                                         |    |                 |
|    | 7.4                                                          | Classification of polymers based on Thermal behavior:  Thermoplastic polymers and Thermosetting polymers.                                                                                                                                                                                                        |    |                 |
|    | 7.5                                                          | Types of polymerizations:   Addition polymerization and Condensation polymerization                                                                                                                                                                                                                              |    |                 |
|    | 7.6                                                          | Preparation (by simple reactions), Properties and Uses of some  thermoplastic polymers and thermosetting polymers:   Polyethylene  (PE),  Polypropylene  (PP),  PolyVinylChloride  (PVC),  PolyTetraFluoroEthylene  (PTFE,  Teflon,  and  Fluon),  Polystyrene  (PS),  PolyAcryloNitrile  (PAN),  Bakelite,  and |    |                 |
|    | 7.7                                                          | Epoxy resins.   Biodegradable  Polymers:  Definition,  Chemical  composition  and  Uses  of  Poly-β-HydroxyButyrate-co-β-hydroxyl  Valerate (PHBV), Nylon-2-nylon-6.                                                                                                                                             |    |                 |
|    | Elastomers (Rubbers):                                        | Elastomers (Rubbers):                                                                                                                                                                                                                                                                                            |    |                 |
|    | 7.8                                                          | Natural rubber and its Properties.                                                                                                                                                                                                                                                                               |    |                 |
|    | 7.9                                                          | Vulcanization of rubber and its   Advantages.                                                                                                                                                                                                                                                                    |    |                 |
|    | 7.10                                                         | Synthetic  rubbers:  Preparation  (by  simple  reactions),  Properties and Uses  of  Buna-S  (GR-S  or  Styrene)  rubber,                                                                                                                                                                                        |    |                 |
|    | Buna-N   (GR-A or Nitrile) rubber, Neoprene (GR-M) rubber.   | Buna-N   (GR-A or Nitrile) rubber, Neoprene (GR-M) rubber.                                                                                                                                                                                                                                                       |    |                 |
|    | 7.11                                                         | Adhesives:   Definition and Characteristics of Adhesives.                                                                                                                                                                                                                                                        |    |                 |
|    | 7.12                                                         | Classification of Adhesives.                                                                                                                                                                                                                                                                                     |    |                 |
|    | 7.13                                                         | Applications of Adhesives.                                                                                                                                                                                                                                                                                       |    |                 |
|    | Semiconductors:                                              | Semiconductors:                                                                                                                                                                                                                                                                                                  |    |                 |
|    | 7.14                                                         | Definition of Semiconductors.                                                                                                                                                                                                                                                                                    |    |                 |
|    | 7.15                                                         | Enlist semiconductor devices.                                                                                                                                                                                                                                                                                    |    |                 |
|    | 7.16                                                         | Elemental Semiconductors:   Intrinsic  Semiconductors,  Extrinsic  Semiconductors  (n-type                                                                                                                                                                                                                       |    |                 |

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## GUJARAT TECHNOLOGICAL UNIVERSITY

Program Name: Diploma in Engineering Level: Diploma

Branch: Sem-1:Chemical Engineering/Textile Processing Technology

Sem-2 :Instrumentation &amp; Control/Textile Manufacturing/

Automation &amp; Robotics/Printing Technology

Course / Subject Code: DI01000161

Course / Subject Name:  Basic Chemistry

| Semiconductors, p-type Semiconductors).   |    |                  |
|-------------------------------------------|----|------------------|
| Total                                     | 45 | 100%  (70 Marks) |

## Suggested Specification Table with Marks (Theory):

## Distribution of Theory Marks (in %)

| R Level          | U Level          | A Level         | N Level   | E Level   | C Level   |
|------------------|------------------|-----------------|-----------|-----------|-----------|
| 24 Marks   (35%) | 32 Marks   (45%) | 14 Marks  (20%) | -         | -         | -         |

Where R: Remember; U: Understanding; A: Application, N: Analyze and E: Evaluate C: Create (as per Revised Bloom's Taxonomy)

Note : This specification table provides general guidelines to assist students for their learning and to teachers to teach and question paper designers/setters to formulate test items/questions to assess the attainment of the UOs. The actual distribution of marks at different taxonomy levels (of R, U and A) in the question paper may slightly vary from above table.

## References/Suggested Learning Resources:

## (a) Books:

|   Sr.  No. | Title of Book                                                | Author                          | Publication with the place, year and ISBN                                                                                                                              |
|------------|--------------------------------------------------------------|---------------------------------|------------------------------------------------------------------------------------------------------------------------------------------------------------------------|
|          1 | Engineering Chemistry                                        | Jain & Jain                     | Dhanpat  Rai  Publishing  Co.  (P)  Ltd.,  New  Delhi, 2015, ISBN: 93-521-6000-2                                                                                       |
|          2 | A  Textbook  of  Engineering Chemistry                       | Dr S. S. Dara &  Dr S. S. Umare | S.  Chand  &  Co.  (P)  Ltd.,  New  Delhi,  2014,  ISBN: 81-219-0359-9                                                                                                 |
|          3 | Textbook of Chemistry  for  Class  XI  &  XII  (Part-I & II) | NCERT                           | NCERT,  New  Delhi,  2017-18,  Class-XI,  ISBN: 81-7450-494-X (Part-I), 81- 7450-535- O  (Part-II),  Class-XII,  ISBN:  81-7450-648- 9(Part-I), 81-7450-716-7(Part-II) |
|          4 | Engineering Chemistry                                        | Shikha Agarwal                  | Cambridge Uni. Press, New Delhi,  2019, ISBN: 978-1-108-72444-9                                                                                                        |

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## GUJARAT TECHNOLOGICAL UNIVERSITY

## Program Name: Diploma in Engineering Level: Diploma

Branch: Sem-1:Chemical Engineering/Textile Processing Technology

Sem-2 :Instrumentation &amp; Control/Textile Manufacturing/

Automation &amp; Robotics/Printing Technology

Course / Subject Code: DI01000161

Course / Subject Name:  Basic Chemistry

|   5 | Understanding  Chemistry          | C. N. R. Rao     | World scientific  publishing  Co.,  2009,  ISBN:  9789812836045    |
|-----|-----------------------------------|------------------|--------------------------------------------------------------------|
|   6 | Engineering Chemistry             | Dr. Vikram, S.   | Wiley  India  Pvt.  Ltd.,  New  Delhi,  2013,  ISBN: 9788126543342 |
|   7 | Chemistry  for  Engineers         | Rajesh Agnihotri | Wiley  India  Pvt.  Ltd.,  2014,  ISBN:  9788126550784             |
|   8 | Fundamental  of  Electrochemistry | V. S. Bagotsky   | Wiley  International  N.J.,  2005,  ISBN:  9780471700586           |

## (b) Open source software and website:

1. http://www.chemguide.co.uk/atommenu.html
2. https://www.visionlearning.com/
3. http://www.chem1.com/
4. https://www.wastewaterelearning.com/elearning/
5. https://www.wqa.org/
6. https://ncert.nic.in/
7. http://www.olabs.edu.in/
8. http://chemcollective.org/activities/type\_page/1
9. http://www.presentingscience.com/vac/corrosion/index.htm
10. https://vlab.amrita.edu/index.php?sub=2&amp;brch=190

## Suggested Course Practical List:

|   Sr.  No. | Practical Outcomes (PrOs)                                                                                                                          |   Unit No. |
|------------|----------------------------------------------------------------------------------------------------------------------------------------------------|------------|
|          1 | Prepare a standard solution of oxalic acid or potassium permanganate.                                                                              |          1 |
|          2 | Prepare a solution of given concentration in terms of percentage weight by  weight (% w/w) of a given compound.                                    |          1 |
|          3 | Prepare a solution of given concentration in terms of percentage volume by  volume (% v/v) of a given compound.                                    |          1 |
|          4 | Prepare a solution of given concentration in terms of percentage weight by  volume (% w/v) of a given compound.                                    |          1 |
|          5 | Determine the strength of the given sodium hydroxide solution by titrating  against standard oxalic acid solution using phenolphthalein indicator. |          1 |
|          6 | Standardize  potassium  permanganate  solution  by  standard  oxalic  acid  solution and estimate ferrous ions.                                    |          2 |
|          7 | Determine  pH-Values  of  given  samples  of  Solution  by  using  Universal                                                                       |          2 |

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## GUJARAT TECHNOLOGICAL UNIVERSITY

## Program Name: Diploma in Engineering

## Level: Diploma

Branch: Sem-1:Chemical Engineering/Textile Processing Technology

Sem-2 :Instrumentation &amp; Control/Textile Manufacturing/

Automation &amp; Robotics/Printing Technology

Course / Subject Code: DI01000161

Course / Subject Name:  Basic Chemistry

|    | Indicator and pH-meter.                                                                                                                            |    |
|----|----------------------------------------------------------------------------------------------------------------------------------------------------|----|
|  8 | Determine emf of an electrochemical cell (Daniel cell).                                                                                            |  2 |
|  9 | Determine electrochemical equivalent of copper metal using Faraday's first  law.                                                                   |  2 |
| 10 | Determine the rate of corrosion for different metals in the given solution.                                                                        |  3 |
| 11 | Determine the rate of corrosion for metal in the solutions of different ph.                                                                        |  3 |
| 12 | Estimate  total  hardness  of  given  water  sample  using  standard  EDTA  solution.                                                              |  4 |
| 13 | Estimate  alkalinity  of  given  water  sample  using  0.01M  sulphuric  acid  solution.                                                           |  4 |
| 14 | Determine Total Dissolved Solid (TDS) and Total Suspended Solid (TSS) in  a given sample of water.                                                 |  4 |
| 15 | Determine the viscosity of the lubricating oil using a Redwood viscometer.                                                                         |  6 |
| 16 | Determine the Acid value of the given lubricating oil.                                                                                             |  6 |
| 17 | Determine the Saponification value of the given lubricating oil.                                                                                   |  6 |
| 18 | Determine  flash  point  and  fire  point  of  the  given  lubricating  oil  using  Pensky Martens/Cleveland open cup/Able's flashpoint apparatus. |  6 |
| 19 | Prepare Polystyrene and Bakelite. (Anyone)                                                                                                         |  7 |

## Note:

- i. Practical Exercises of at least 28 Hrs . should be completed by the end of the term.
- ii. More Practical  Exercises can  be  designed  and  offered  by  the  respective  course  teacher  to develop  the  industry-relevant  skills/outcomes  to  match  the  COs.  The  above  table  is  only  a suggestive list.
- iii. The  following  are  some sample  'Process' and 'Product'  related  skills (more  may  be added/deleted depending on the course) that occur in the above listed Practical Exercises of this course required which are embedded in the COs and ultimately the competency.

| Sr. No.   | Sample Performance Indicators for the PrOs                                                                  | Weightage in  %          | Maximum  Marks for  PA/CA (I)   |
|-----------|-------------------------------------------------------------------------------------------------------------|--------------------------|---------------------------------|
|          | 'Process' related skills                                                                                    | 'Process' related skills | 'Process' related skills        |
| 1.        |   Prepare experimental setup accurately.   Handling  of  apparatus/glassware  for  precise  measurements. | 20                       | 4                               |

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## GUJARAT TECHNOLOGICAL UNIVERSITY

## Program Name: Diploma in Engineering

## Level: Diploma

Branch: Sem-1:Chemical Engineering/Textile Processing Technology

Sem-2 :Instrumentation &amp; Control/Textile Manufacturing/

Automation &amp; Robotics/Printing Technology

Course / Subject Code: DI01000161

Course / Subject Name:  Basic Chemistry

| 2.    |   Practice and adapt good and safe measuring techniques.     Record observations correctly.   | 20                       | 4                        |
|-------|-------------------------------------------------------------------------------------------------|--------------------------|--------------------------|
| 3.    |   Housekeeping.    Observance /Follow safety rules.                                           | 20                       | 4                        |
|      | 'Product' related skills                                                                        | 'Product' related skills | 'Product' related skills |
| 4.    |   Does Calculations.    Interpret the Results and their Conclusion/s.                         | 20                       | 4                        |
| 5.    |   Prepare report of practical in prescribed format.    Viva-voce.                             | 20                       | 4                        |
| Total | Total                                                                                           | 100                      | 20                       |

## List of Laboratory Equipment's required:

|   No. | Equipment's / Instruments                                                            | Practical   No.                   |
|-------|--------------------------------------------------------------------------------------|-----------------------------------|
|     1 | Electronic  Weighing  Balance  /  Digital  Weighing  Balance (OR Analytical Balance) | 1,  6,  7,  8,  11,  13,  14,  16 |
|     2 | Hot plate with Magnetic stirrer                                                      | 3                                 |
|     3 | Digital pH meter                                                                     | 4, 8                              |
|     4 | Voltmeter                                                                            | 5                                 |
|     5 | 6 V Battery                                                                          | 6                                 |
|     6 | Ammeter                                                                              | 6                                 |
|     7 | Rheostat                                                                             | 6                                 |
|     8 | Dryer                                                                                | 7, 8                              |
|     9 | Hot air oven                                                                         | 11                                |
|    10 | Vacuum Pumps with glass filter                                                       | 11                                |
|    11 | Redwood viscometer No.1                                                              | 12                                |
|    12 | Stop watch                                                                           | 12                                |
|    13 | Pensky-Marten's apparatus OR Cleveland open  cup OR Abel's flashpoint apparatus      | 15                                |

## Suggested Project List:

1. Prepare a model of an atom with the help of a ball and stick or of any other items.

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## GUJARAT TECHNOLOGICAL UNIVERSITY

Program Name: Diploma in Engineering Level: Diploma

Branch: Sem-1:Chemical Engineering/Textile Processing Technology Sem-2 :Instrumentation &amp; Control/Textile Manufacturing/ Automation &amp; Robotics/Printing Technology Course / Subject Code: DI01000161 Course / Subject Name:  Basic Chemistry

2. Prepare a PowerPoint animation that can explain the structure of an atom.
3. Prepare a chart showing (1) Atomic number (Z = e -= p + ) 1 to 30, (2) Name of the element, (3) Symbol, (4) Electronic configuration and (5) Condensed Electronic configuration of elements in tabular form.
4. Prepare a chart of the modern periodic table which gives information about the atomic number and mass number of different elements.
5. Prepare crystals of common salt from NaCl solution.
6. Form three  groups  of  students  in  the  class.  Consider  a  hypothetical  situation  of  exchanging/ sharing/giving of different items/belongings and demonstrate the type of ionic, covalent, and co-ordinate bonding amongst the students in a simulated situation. Present your findings.
7. Prepare a chart representing compounds and solutions which affect human life positively and negatively.
8. Classify the surrounding corrosion into dry corrosion and wet corrosion.
9. Collect different samples of utensils reinforced materials, iron, copper, brass, bronze, and other alloys. Place them in an open environment under tin shade. Observe the corrosive properties over a period of four weeks. Record your observations. Discuss the findings with your teacher and classmates.
10. Collect  three  metallic  strips  of  Cu,  Al  and  Fe.  Place  them  in  different  acidic  and  alkaline solutions of the same concentration. Observe and record the loss in weight of metals due to an acidic and alkaline environment. Discuss the findings with your teacher and classmates.
11. Prepare a model to demonstrate the application of electrolysis.
12. Collect water samples from different water sources and measure the hardness of the water.
13. Collect  the  water  sample  from  different  sources  of  ground  and  surface  water  (at  least  five). Explore the new and simplest softening and water treatment methods by creating the different assemblies and manipulative techniques.

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## GUJARAT TECHNOLOGICAL UNIVERSITY

Program Name: Diploma in Engineering Level: Diploma

Branch: Sem-1:Chemical Engineering/Textile Processing Technology Sem-2 :Instrumentation &amp; Control/Textile Manufacturing/ Automation &amp; Robotics/Printing Technology Course / Subject Code: DI01000161 Course / Subject Name:  Basic Chemistry

14. Collect samples of petrol, kerosene, diesel, any edible oil, coconut oil. Find out the flash point and fire point, cloud point and pour point, and viscosity of the same. Compare the properties and justify their use in relevant applications.
15. Depending on the type of machinery, the load applied, speed of the machine, heat generated, etc., select the appropriate lubricant which can be applied to the machinery. Discuss with your teachers and classmates and present the same.
16. Make a table showing the availability of natural rubber in India and show places on the map of India.
17. Prepare  a  chart  showing  (1)  name  &amp;  formula  of  the  Polymer,  (2)  name  and  formula  of  the Monomer/s  used  to  prepare  that  polymer,  (3)  simple  reaction  equation  for  Preparation  of polymer, (4) Properties in short and (5) Uses in tabular form.
18. Collect different polymers and prepare the chart/ PowerPoint based on their type, properties, and uses.
19. Classify Semiconductors with examples. Enlist Semiconductor Devices. Also collect Semiconductors.

## Suggested Activities for Students:

1. Prepare  a  Power  point  presentation  or  animation  showing  different  atomic  structures  and different types of chemical bonds.
2. Calculate pH of acid solutions and base solutions having different concentrations.
3. Prepare a chart showing different methods used for the prevention of corrosion.
4. Enlist the formulae to solve the numericals based on hardness of water. Calculate the Molecular mass of salts responsible for hardness of water. Show calculations for some numericals based on hardness of water.

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## GUJARAT TECHNOLOGICAL UNIVERSITY

Program Name: Diploma in Engineering Level: Diploma

Branch: Sem-1:Chemical Engineering/Textile Processing Technology Sem-2 :Instrumentation &amp; Control/Textile Manufacturing/ Automation &amp; Robotics/Printing Technology Course / Subject Code: DI01000161 Course / Subject Name:  Basic Chemistry

5. Prepare a table showing the points of differences between organic compounds and inorganic compounds.
6. Do market survey of different types of lubricating oils and compare their physical properties and chemical properties.
7. Do library survey regarding polymers, synthetic rubbers, adhesives and semiconductors used in different industries.

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